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It is possible to have a reduction in absolute synthesis rates without a change in fractional synthesis rates because pool size, a determinant of absolute synthesis rates, can vary for the same fractional synthesis rates

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The acrylamide warhead on ibrutinib and zanubrutinib has a GSH half-life of 33 h, while spebrutinib warhead acyl-acrylamide has a half-life of ~1.6 h [107]